Whether you make chili for the big game or with big game, start this big batch recipe the day before you plan to serve it. The generous pour of aged rum added at the end of simmering is key to the flavorful complexity in this recipe. Grabbing a bottle from the bar cart or beverage fridge isn’t necessarily novel when it comes to chili. A few glugs of Bloody Mary mix, stout, or bourbon are all common additions. But they are more typically incorporated as a component of the braising liquid or used to deglaze the pan after browning the meat, which means the flavors dissipate and get muddied over hours of simmering. Here, adding the rum (I like Campesino) during the last 15 or so minutes allows its distinctive notes of caramel, honey, and oak to bloom, mellow, and meld perfectly. Consider it like adding a splash of vinegar, citrus juice, or a drizzle of really fruity olive oil to brighten a dish at the end of cooking.
